Ontology learning from texts has recently been proposed as a new technology helping ontology designers in the modelling process. Discovery of non–taxonomic relations is understood as the least tackled problem therein. We propose a technique for extraction of lexical entries that may give cue in assigning semantic labels to otherwise ‘anonymous’ relations. The technique has been implemented as extension to the existing Text-to-Onto tool, and tested on a collection of texts describing worldwide geographic locations from a tour–planning viewpoint.