We study approximations of optimization problems with probabilistic constraints in which the original distribution of the underlying random vector is replaced with an empirical distribution obtained from a random sample. We show that such a sample approximation problem with risk level larger than the required risk level will yield a lower bound to the true optimal value with probability approaching one exponentially fast. This leads to an a priori estimate of the sample size required to have high confidence that the sample approximation will yield a lower bound. We then provide conditions under which solving a sample approximation problem with a risk level smaller than the required risk level will yield feasible solutions to the original problem with high probability. Once again, we obtain a priori estimates on the sample size required to obtain high confidence that the sample approximation problem will yield a feasible solution to the original problem. Finally, we present numerical il...