Abstract. During this decade, it has been observed that many realworld graphs, like the web and some social and metabolic networks, have a scale-free structure. These graphs are characterized by a big variability in the arity of nodes, that seems to follow a power-law distribution. This came as a big surprise to researchers steeped in the tradition of classical random networks. SAT instances can also be seen as (bi-partite) graphs. In this paper we study many families of industrial SAT instances used in SAT competitions, and show that most of them also present this scale-free structure. On the contrary, random SAT instances, viewed as graphs, are closer to the classical random graph model, where arity of nodes follows a Poisson distribution with small variability. This would explain their distinct nature. We also analyze what happens when we instantiate a fraction of the variables, at random or using some heuristics, and how the scale-free structure is modified by these instantiations....