Underwater acoustic communications systems are challenged by the characteristics of acoustic propagation through the underwater environment. There are a wide range of physical processes that impact underwater acoustic communications and the relative importance of these processes are different in different environments. In this paper some relevant propagation phenomena are described in the context of how they impact the development and/or performance of underwater acoustic communications networks. The speed of sound and channel latency, absorption and spreading losses, waveguide effects and multipath, surface scattering, bubbles, and ambient noise are all briefly discussed. Categories and Subject Descriptors: A.1 [General]: Introductory and Survey General Terms: Algorithms, Performance, Reliability