As a sequence of two or more consecutive individual words inherent with contextual semantics of individual words, multi-word attracts much attention from statistical linguistics and of extensive applications in text mining. In this paper, we carried out a series studies on multi-word extraction from Chinese documents. Firstly, we proposed a new statistical method, augmented mutual information (AMI), for words’ dependency. Experiment results demonstrate that AMI method can produce a recall on average as 80% and its precision is about 20%-30%. Secondly, we attempt to utilize the variance of occurrence frequencies of individual words in a multi-word candidate to deal with the rare occurrence problem. But experimental results cannot validate the effectiveness of variance. Thirdly, we developed a syntactic method based on lexical regularities of Chinese multi-word to extract the multi-words from Chinese documents. Experimental results demonstrate that this syntactical method can produce a...