Scientists increasingly rely on the execution of workflows in grids to obtain results from complex mixtures of applications. However, the inherently dynamic nature of grid workflow scheduling, stemming from the unavailability of scheduling information and from resource contention among the (multiple) workflows and the non-workflow system load, may lead to poor or unpredictable performance. In this paper we present a comprehensive and realistic investigation of the performance of a wide range of dynamic workflow scheduling policies in multicluster grids. We first introduce a taxonomy of grid workflow scheduling policies that is based on the amount of dynamic information used in the scheduling process, and map to this taxonomy seven such policies across the full spectrum of information use. Then, we analyze the performance of these scheduling policies through simulations and experiments in a real multicluster grid. We find that there is no single grid workflow scheduling policy with goo...